Adsorption and catalytic degradation of bisphenol A and p-chlorophenol by magnetic carbon nanotubes

Phenolic compounds are common industrial pollutants that seriously endangers water ecology and human health. Therefore, the development of efficient and recyclable adsorbents is of importance for wastewater treatment. In this research, HCNTs/Fe3O4 composites were constructed using co-precipitation way by loading magnetic Fe3O4 particles onto hydroxylated multi-walled carbon nanotubes (MWCNTs), showing excellent adsorption capacity for Bisphenol A (BPA) and p-chlorophenol (p-CP), and excellent catalytic ability of activating potassium persulphate (KPS) for degradation of BPA and p-CP. The adsorption capacity and catalytic degradation potential were evaluated for the removal of BPA and p-CP from solutions. The results showed that the adsorption took only 1 h to reach equilibrium and HCNTs/Fe3O4 had maximum adsorption capacities of 113 mg g−1 for BPA and 41.6 mg g−1 for p-CP at 303 K, respectively. The adsorption of BPA fitted well using the Langmuir, Temkin and Freundlich models while the adsorption of p-CP fitted well using the Freundlich and Temkin models. BPA adsorption on HCNTs/Fe3O4 was dominated by π-π stacking and hydrogen bonding forces. The adsorption included both the mono-molecular layer adsorption on the adsorbent surface and the multi-molecular layer adsorption on the non-uniform surface. The adsorption of p-CP on HCNTs/Fe3O4 was a multi-molecular layer adsorption on a dissimilar surface. The adsorption was controlled by forces such as π-π stacking, hydrogen bonding, partition effect and molecular sieve effect. Moreover, KPS was added to the adsorption system to initiate a heterogeneous Fenton-like catalytic degradation. Over a wide pH range (4–10), 90% of the aqueous BPA solution and 88% of the p-CP solution were degraded in 3 and 2 h, respectively. After three adsorption-regeneration or degradation cycles, the removal of BPA and p-CP remained up to 88% and 66%, indicating that HCNTs/Fe3O4 composite is cost-effective, stable and highly efficient to remove BPA and p-CP from solution.