甲脒
三碘化物
材料科学
掺杂剂
锡
兴奋剂
锂(药物)
碘化物
纳米技术
化学工程
无机化学
物理化学
光电子学
化学
色素敏化染料
内分泌学
冶金
电解质
电极
医学
工程类
作者
Manman Hu,Andi Muhammad Risqi,Jianchang Wu,Chunjun Liang,Jaewang Park,Seungun Lee,Hyun‐Sung Yun,Byung‐wook Park,Christoph J. Brabec,Sang Il Seok
标识
DOI:10.1002/adfm.202300693
摘要
Abstract Improving the performance, reproducibility, and stability of Sn‐based perovskite solar cells (PSCs) with n–i–p structures is an important challenge. Spiro‐OMeTAD [2,2′,7,7′‐tetrakis (N,N ‐di‐ p ‐methoxyphenyl‐amine)9,9′‐spirobifluorene], a hole transporting material (HTM) with n–i–p structure, requires the oxygen exposure after addition of Li‐TFSI [Lithium bis(trifluoromethanesulfonyl)imide] as a dopant to increase the hole concentration. In Sn‐based PSC, Sn 2+ is easily oxidized to Sn 4+ under such a condition, resulting in a sharp decrease in efficiency. Herein, a formamidinium tin triiodide (FASnI 3 )‐based PSCs fabricated using DPI‐TPFB [4‐Isopropyl‐4′‐methyldiphenyliodonium tetrakis(pentafluorophenyl)borate] instead of Li‐TFSI are reported as a dopant in Spiro‐OMeTAD. The DPI‐TPFB enables the fabrication of PSCs with an efficiency of up to 10.9%, the highest among FASnI 3 ‐based PSCs with n–i–p structures. Moreover, ≈80% of the initial efficiency is maintained even after 1,597 h under maximum power point tracking conditions. In particular, the encapsulated device does not show any decrease in efficiency even after holding for 50 h in the 85 °C/85% RH condition. The high efficiency and excellent stability of PSCs prepared by doping with DPI‐TPFB are attributed to not only increasing electrical conductivity by acting as a Lewis acid, but also stabilizing Sn 2+ through coordination with Sn 2+ on the surface of FASnI 3 .
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