Superspreading Surface with Hierarchical Porous Structure for Highly Efficient Vapor–Liquid Phase Change Heat Dissipation

Abstract Superspreading surfaces with excellent water transport efficiency are highly desirable for addressing thermal failures through the liquid–vapor phase change of water in electronics thermal management applications. However, the trade‐off between capillary pressure and viscous resistance in traditional superspreading surfaces with micro/ nanostructures poses a longstanding challenge in the development of superspreading surfaces with high cooling efficiency in confined spaces. Herein, a heat‐treated hierarchical porous enhanced superspreading surface (HTHP) for highly efficient electronic cooling is proposed. Compared with the single porous structures in nanograss, nanosheets, and copper foam, HTHP with hierarchical honeycomb pores effectively resolves the trade‐off effect by introducing large vertical through‐pores to reduce viscous resistance, and connected small pores to provide sufficient capillary pressure synergistically. HTHP exhibits excellent capillary performance in both horizontal spreading and vertical rising. Despite a thickness of only 0.33 mm, the as‐prepared ultrathin vapor chamber (UTVC) fabricated to exploit the superior capillary performance of HTHP achieved effective heat dissipation with outstanding thermal conductivity (12 121 Wm −1 K −1 ), and low thermal resistance (0.1 KW −1 ) at a power of 5 W. This regulation strategy based on hierarchical honeycomb porous structures is expected to promote the development of high‐performance superspreading surfaces with a wide range of applications in thermal management.