Wide Electrochemical Stability Window of NaClO4 Water-in-Salt Electrolyte Elevates the Supercapacitive Performance of Poly(3,4-ethylenedioxythiophene)

Water-in-salt electrolytes (WiSEs) have emerged as the primary preference in the domain of aqueous-based supercapacitors, thanks to their wide electrochemical stability window (ESW > 1.23 V). Here, we have chemically synthesized a unique lettuce coral-like structure of tosylate doped-poly(3,4-ethylenedioxythiophene) (PEDOT-tos) and tested it for supercapacitor application in a 17 molal (m) NaClO4 WiSE, achieving an ESW of 1.9 V. The energy and power densities (Ed and Pd) of our PEDOT-tos supercapacitor are as high as 14 Wh/kg and 7210 W/kg, respectively, with over 80% capacitance retention after 10,000 continuous Galvanostatic charge-discharge cycles. The NaClO4 WiSE increases the Ed and Pd of PEDOT by several folds compared to traditional H2SO4 electrolyte. This work encourages the exploration of a suitable combination of a PEDOT-based composite material and WiSE for high-performance supercapacitors.