Construction of COF/COF Organic S‐Scheme Heterostructure for Enhanced Overall Water Splitting

, respectively, under visible light irradiation (λ ≥ 420 nm). The results of transient absorption spectra (TAS) and photoelectronic measurements indicate that the organic heterojunction interface notably facilitates the separation and transfer of photogenerated electron-hole pairs. Further, theoretical calculations and in situ experiments confirm the spontaneous formation of the COF/COF heterojunction interface and the active sites for overall water splitting.