沸石咪唑盐骨架
金属有机骨架
吸附
纳米技术
光催化
材料科学
咪唑酯
水溶液中的金属离子
污染物
环境化学
金属
化学
无机化学
有机化学
催化作用
冶金
作者
Smriti Rana,Yogesh Kumar,Rahul Kaushik,Lalita S. Kumar
标识
DOI:10.1002/slct.202403309
摘要
Abstract Heavy metals, pharmaceuticals, microplastics, dyes, and radionuclides in wastewater increasingly threaten environmental sustainability. Metal‐organic frameworks (MOFs) are versatile materials for mitigating these contaminants through efficient detection, capture, adsorption, and degradation. These crystalline structures, formed by combining metal ions with organic ligands, offer high surface area, tailored porosity, reproducibility, and robust chemical stability. This review compiles recent advancements in MOFs for pollutant removal, highlighting innovations in selective adsorption mechanisms for heavy metals, functionalized MOFs for pharmaceutical and microplastic removal, and enhanced photocatalytic degradation for dyes. Unique to this review is the integration of recent innovations such as ion exchange capabilities and photocatalytic degradation under visible light, addressing advanced applications that significantly enhance pollutant removal efficiency that other reviews have not covered comprehensively. The review also cites our group's recent work on a curcumin‐immobilized zeolitic imidazolate framework‐8 (Cmim@ZIF‐8) nanoprobe, demonstrating high selectivity for Fe 2+ ions in water (detection limit: 7.64 μM) and its applicability in live‐cell imaging of HepG2 cells. Advanced techniques like density functional theory (DFT) simulations are employed to elucidate adsorption and degradation mechanisms, bridging theoretical insights with experimental findings. By critically evaluating these developments, the review identifies promising avenues for optimizing MOF design and advancing effective water treatment solutions.
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