材料科学
离子液体
韧性
极限抗拉强度
聚合
聚合物
软机器人
纳米技术
离子键合
粘附
复合材料
化学工程
离子
计算机科学
人工智能
机器人
生物化学
化学
物理
量子力学
工程类
催化作用
作者
Jianfei Tie,Zhiping Mao,Linping Zhang,Yi Zhong,Hong Xu
标识
DOI:10.1002/adfm.202307367
摘要
Abstract Ionogels have become a popular material in flexible electronics and soft robotics based on their excellent ionic conductivity, environmental tolerance, and electrochemical stability. However, it remains a challenge to develop an ionogel integrated with high strength, toughness, self‐healing, and adhesion. Herein, a novel strategy is established to design a high‐strength (0.97 MPa) and tensile (980%), excellent crack insensitivity, self‐healing ionogel based on the cosolvent method. By virtue of differential interactions between the specific polymer and various ionic liquids with gradient polarity, cosolvent systems are employed to achieve high‐performance ionogels by a simple one‐step polymerization. Gel permeation chromatography, atomic force microscopy, time‐domain nuclear magnetism, and density functional theoretical calculation are used to analyze the reasons. Microphase separation can be induced by hydrone or stretching to enhance strength of the ionogel. Therefore, ionogels can be assembled as strain and temperature sensors to monitor human movement and person's body temperature with a low detection threshold (0.1 °C) in extreme environments. This concept creates a new path to achieve soft materials with high performance, and provide a prospective strategy to regulate the in situ microphase change and performance of the resulting ionogel via the one‐step polymerization.
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