Preparation and Characterization of ZnTiO3/g‐C3N4 Heterojunction Composite Catalyst with Highly Enhanced Photocatalytic CO2 Reduction Performance

Herein, well‐crystallized ZnTiO 3 particles are first prepared by hydrothermal method. A series of S‐scheme heterojunction photocatalysts of ZnTiO 3 /g‐C 3 N 4 (referred to as ZTO/CN) with different mass ratios are synthesized by successfully doping ZnTiO 3 in g‐C 3 N 4 precursors and loading ZnTiO 3 onto g‐C 3 N 4 nanosheets by calcination. It is clearly found that the ZnTiO 3 particles are successfully loaded on g‐C 3 N 4 nanosheets by the X‐ray diffractometer, energy‐dispersive X‐ray spectra, and high‐resolution transmission electron microscopy images. Moreover, the specific surface area of 3.0% ZTO/CN is higher than that of pure g‐C 3 N 4 . Using triethanolamine as the hole sacrificial agent, the highest CO and H 2 yields are achieved in the 3.0% ZTO/CN composite catalyst under the xenon lamp irradiation for 1 h. The generation rates of CO and H 2 reach 15.19 and 5.77 μmol g −1 h −1 , respectively, which are 2.9 and 4.1 times higher than that of pure g‐C 3 N 4 . The CO and H 2 yields of the ZTO/CN composite catalyst show a trend of increasing and then decreasing with the increasing of ZnTiO 3 content, which is due to the fact that excess ZnTiO 3 can lead to a reduction of the effective heterojunction interface between ZnTiO 3 and g‐C 3 N 4 , decreasing the transfer and separation efficiency of photogenerated electrons and holes and thus reducing the photocatalytic activity.