Efficient full spectrum responsive photocatalytic NO conversion at Bi2Ti2O7: Co-effect of plasmonic Bi and oxygen vacancies

Developing full-spectrum responsive and efficient photocatalysts is still important challenge in the field of photocatalytic treatment of trace environmental pollutants. Herein, full-spectrum Bi@Bi 2 Ti 2 O 7 with rich-oxygen vacancy (OVs) were fabricated via a one-pot hydrothermal method. The optimized composite photocatalyst exhibited a photocatalytic efficiency of 79%, more than doubled higher than that of its counterpart, Bi 2 Ti 2 O 7 (31.79%), for removing ppb-level NO under visible-near infrared (Vis-NIR) irradiation. The enhanced photocatalytic performance was attributed to the co-effect of Bi and OVs reveal by control experiments and theoretical calculations, which not only benefited the adsorption and photocatalytic activation of NO but broadened light absorption to near infrared. Furthermore, the adsorption and photocatalytic conversion pathway of NO was explored by in situ DRIFTS, suggesting that NO + as intermediate species is crucial to improve the selectivity of NO converting to nitrate. This work provides a new perspective of constructing full-spectrum-driven photocatalysts for environment remediation. Full-spectrum responsive Bi@Bi 2 Ti 2 O 7 -OV with plasmonic Bi and oxygen vacancies exhibited a photocatalytic efficiency of 79% for removing ppb-level NO, more than doubled higher than that of its counterpart (Bi 2 Ti 2 O 7 , 31.79%). The synergistic effect of plasmonic Bi and oxygen vacancies not only improved the adsorption and photocatalytic activation of NO but broadened light absorption to near infrared, resulting in enhanced photocatalytic performance. • Full-spectrum Bi@Bi 2 Ti 2 O 7 -OV exhibited efficient photocatalytic removal of NO. • The enhanced photocatalytic activity was attributed to co-effect of Bi and OVs. • The photocatalytic mechenism and pathway were proposed by in situ DRIFTS.