Dynamic ion exchange engineering bismuth ferrite-derived Bi2O2CO3 for rapid piezo-photocatalytic degradation of tetracycline

Piezoelectric materials can generate the built-in electric field under ultrasound assistance, which is beneficial to the separation of the photogenerated electron-hole pairs in photocatalysis. Meanwhile, the ultrasound stress usually leads to accelerate electron transfer and enhance catalytic activity. Thus, piezo-photocatalysis technique is believed to be one of the effective techniques for organic pollutant degradation. In this work, a binary piezoelectric integrated piezo-photocatalytic Z-Scheme heterojunction with bismuth ferrite (BFO) and bismuth oxycarbonate (Bi2O2CO3, BOC) based on the in situ production of Bi2O2CO3 on Bi25FeO40 surface in dichloromethane, where Bi25FeO40 was employed as piezoelectric materials and Bi source, CO2 dissolved in dichloromethane was used as carbon source. Under 60 min ultrasound and visible light irradiation, the optimal BFO/BOC presented a higher piezo-photocatalytic tetracycline (TC) degradation rate (95 %) than Bi25FeO40 (30 %) and Bi2O2CO3 (17 %). Moreover, the optimal BFO/BOC illustrated higher piezo-photocatalytic TC degradation rate under ultrasound and visible light irradiation than that under visible light condition and ultrasound condition, respectively. These results strongly demonstrated the synergistically piezo-photocatalytic degradation of TC by BFO and BOC. This work not only provides a novel piezo-photocatalyst for pollutant degradation, but also provides a novel method to prepare Bi2O2CO3-based piezo-photocatalytic composite catalyst.