Effects of adding methods and modification types of cellulose on the physicochemical properties of starch/PBAT blown films

This study revealed the relationship between cellulose types/adding methods and film properties, in which sodium carboxymethyl cellulose (CMC), hydroxypropyl methyl cellulose (HPMC), and microcrystalline cellulose (MCC) were added into starch/PBAT blown films in powder, aqueous solution, and emulsion forms, respectively. Cellulose interacted with starch networks via hydrogen bonds, and those added in emulsion form made more homogeneous film morphologies. MCC emulsion enhanced the film strength (40%) and modulus (149%) to the greatest extent, while comprehensively, HPMC emulsion possessed better reinforcement effects on the films, which increased mechanical properties (31% ~ 100%), moisture barrier (20%), oxygen barrier (93%), surface hydrophobicity (20%), as well as water resistance (12% ~ 76%). Findings supported the application of cellulose in high-throughput biodegradable films, and the high-content starch/PBAT blown films reinforced by HPMC emulsion had great potential in commercial packaging fields.