电解质
材料科学
硅酸钠
氢氧化钾
镁
涂层
电化学
腐蚀
氢氧化钠
钾
无机化学
钠
氟化物
化学工程
冶金
电极
化学
复合材料
物理化学
工程类
作者
Hairong Dong,Qiang Li,Dongbai Xie,Weiguo Jiang,Haijuan Ding,Sheng Wang,Lingyun An
标识
DOI:10.1016/j.ceramint.2023.07.202
摘要
To systematically investigates the forming ability and properties of micro-arc oxidation (MAO) coatings on magnesium alloys using different types of single electrolytes and further enhance the understanding of the coating formation mechanism from multiple perspectives. MAO treatments were performed in three types of single electrolyte solutions containing either sodium silicate, potassium fluoride, or sodium hydroxide, which were severally designed in terms of main salts, additives, and alkaline substances. The results show that MAO coatings could still be formed in the three single electrolyte solutions; however, the sparks and observable phenomena on the sample surface differed obviously from those in multicomponent electrolytes. In potassium fluoride and sodium hydroxide electrolytes, sparks occurred continuously at fixed positions on the sample surface, forming concave defects with uneven distributions of Mg, F, and O on the coating surface. In addition, a larger response current was observed in the sodium hydroxide electrolyte during MAO; this is disadvantageous in reducing energy consumption. The coating obtained in the potassium fluoride electrolyte had the highest thickness and number of micropores because of the synergy between the electrochemical process and the spark state on the sample surface. In contrast, the coating prepared in the sodium silicate electrolyte exhibited better corrosion resistance because of a certain thickness and good compactness.
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