Pt Nanoparticles Embedded Polypyrrole‐Carbon Black/SrSnO3 Photocatalyst with Stable and Superior Photodegradation Performance

光催化 材料科学 X射线光电子能谱 纳米复合材料 傅里叶变换红外光谱 漫反射红外傅里叶变换 化学工程 三元运算 光降解 纳米技术 核化学 催化作用 化学 有机化学 工程类 计算机科学 程序设计语言
作者
M. Faisal,Jahir Ahmed,Jari S. Algethami,Ali S. Alkorbi,Farid A. Harraz
出处
期刊:ChemistrySelect [Wiley]
卷期号:9 (18)
标识
DOI:10.1002/slct.202304228
摘要

Abstract Currently, the primary focus for scientific authorities and regulatory departments revolves around water pollution. In this regard, photocatalysis has emerged as a highly effective, affordable, and goal‐oriented approach. Thus, recognizing the urgency of this issue, we focused our efforts towards developing a novel ternary photocatalytic structure based on mesoporous SrSnO 3 , combined with polypyrrole‐doped carbon black (PPC) and platinum nanoparticles (Pt NPs). Pt NPs, PPC and SrSnO 3 ‐based nanocomposite photocatalyst was developed through a very simple chemical method followed by ultrasonication and photoreduction techniques. XRD analysis confirmed orthorhombic phase of SrSnO 3 , while the formation of the ternary nanocomposite among Pt NPs, PPC and SrSnO 3 has been confirmed by X‐ray photoelectron spectroscopy (XPS) and Fourier Transform Infrared (FTIR) spectroscopy. Transmission electron microscopy (TEM) revealed the presence of Pt NPs (5–15 nm), beads/dense cocoon like structures of PPC along with rod, spherical and needle shape nanostructures of SrSnO 3 in newly created ternary photocatalyst. Diffuse reflectance spectroscopy (DRS) showed lowering of band gap energy in case of Pt@PPC/SrSnO 3 . Newly developed Pt@PPC/SrSnO 3 nanocomposite worked efficiently when employed on colorless insecticide imidacloprid (IMD) and on colored methylene blue (MB) dye under UV‐light. Pt@PPC/SrSnO 3 photocatalyst exhibited excellent performance with 96.03 % removal of pollutant IMD in only 20 min, almost 296 % more efficient than bare SrSnO 3 . Furthermore, the Pt@PPC/SrSnO 3 ternary photocatalyst showed rapid removal of MB with almost total elimination of dye molecule in just 16 min.

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