纳滤
海水淡化
界面聚合
膜
单体
聚酰胺
氯化物
化学
化学工程
反渗透
选择性
材料科学
色谱法
高分子化学
有机化学
聚合物
工程类
生物化学
催化作用
作者
Jing Dou,J. Han,Saisai Lin,Zhifu Qi,Feipeng Huang,Xiangdong Feng,Zhikan Yao,Jing Wang,Lin Zhang
标识
DOI:10.1016/j.memsci.2023.121382
摘要
Nanofiltration is a promising technology to recover dye from textile wastewater with highly saline for sustainable resource recovery. However, it is difficult for the conventional piperazine-based nanofiltration membranes, which usually have a tight polyamide matrix structure, to precisely separate dye and salt in wastewater. In this study, 5,5,6’,6’-tetrahydroxy-3,3,3’,3’-tetramethyl spirobisindane (TTSBI) with rigidly contorted structure has been used instead of piperazine as aqueous-phase monomer to fabricate polyarylate (PAT) nanofiltration membranes with quasi-PIMs structure via interfacial polymerization (IP) with three types of acyl chloride, i.e., rigid trimesoyl chloride (TMC), short-chain glutaryl chloride (GC) and long-chain sebacoyl dichloride (SDC). The contorted structure of TTSBI introduces extra microporosity in nanofiltration membranes, and the differentia of three acyl chlorides in molecular flexibility further endows with tailoring the stacking density of as-formed PAT networks. The PAT NF membranes thereby exhibited high permeability and tunable size-selectivity in desalination from dye effluent. Among these PAT membranes, TTSBI-TMC membranes had the highest water flux of 480.5 LMH, nearly 7-fold increase compared traditional PA NF membranes, whereas TTSBI-SDC membranes had the highest dye rejection of 97.4%, and TTSBI-GC membrane had the relatively balanced dye desalination performance with high rejection 95.4% for Congo Red and 8.3% for NaCl accompanied by high flux of 402.4 LMH. Therefore, this study provides a new prospective for the fabrication of highly permeable nanofiltration membranes for precise separation.
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