Achieving the Trade‐Off between Selectivity and Activity in Semihydrogenation of Alkynes by Fabrication of (Asymmetrical Pd@Ag Core)@(CeO2 Shell) Nanocatalysts via Autoredox Reaction

Advanced MaterialsVolume 29, Issue 8 1605332 Communication Achieving the Trade-Off between Selectivity and Activity in Semihydrogenation of Alkynes by Fabrication of (Asymmetrical Pd@Ag Core)@(CeO2 Shell) Nanocatalysts via Autoredox Reaction Shuyan Song, Shuyan Song State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorKai Li, Kai Li State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorJing Pan, Jing Pan State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorFan Wang, Fan Wang State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039 P. R. ChinaSearch for more papers by this authorJunqi Li, Junqi Li State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039 P. R. ChinaSearch for more papers by this authorJing Feng, Jing Feng State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorShuang Yao, Shuang Yao State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorXin Ge, Xin Ge State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorXiao Wang, Corresponding Author Xiao Wang skybyyn@ciac.ac.cn State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaE-mail: skybyyn@ciac.ac.cn, hongjie@ciac.ac.cnSearch for more papers by this authorHongjie Zhang, Corresponding Author Hongjie Zhang hongjie@ciac.ac.cn State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaE-mail: skybyyn@ciac.ac.cn, hongjie@ciac.ac.cnSearch for more papers by this author Shuyan Song, Shuyan Song State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorKai Li, Kai Li State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorJing Pan, Jing Pan State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorFan Wang, Fan Wang State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039 P. R. ChinaSearch for more papers by this authorJunqi Li, Junqi Li State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039 P. R. ChinaSearch for more papers by this authorJing Feng, Jing Feng State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorShuang Yao, Shuang Yao State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorXin Ge, Xin Ge State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaSearch for more papers by this authorXiao Wang, Corresponding Author Xiao Wang skybyyn@ciac.ac.cn State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaE-mail: skybyyn@ciac.ac.cn, hongjie@ciac.ac.cnSearch for more papers by this authorHongjie Zhang, Corresponding Author Hongjie Zhang hongjie@ciac.ac.cn State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. ChinaE-mail: skybyyn@ciac.ac.cn, hongjie@ciac.ac.cnSearch for more papers by this author First published: 19 December 2016 https://doi.org/10.1002/adma.201605332Citations: 64Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract (Asymmetrical Pd@Ag core)@(CeO2 shell) nanostructures are successfully fabricated via a clean and facile modified autoredox reaction by the preaddition of Pd seeds in the growth solution. In a subsequent catalytic test, it is found that the as-obtained bimetallic core@shell nanoparticles exhibit excellent catalytic performance in semihydrogenation of alkynes. The trade-off between selectivity and activity is well realized. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description adma201605332-sup-0001-S1.pdf7.4 MB Supplementary Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume29, Issue8February 24, 20171605332 RelatedInformation