塔菲尔方程
介电谱
盐酸
吸附
材料科学
腐蚀
柠檬酸
碳钢
热解
核化学
朗缪尔吸附模型
X射线光电子能谱
电化学
碳纤维
无机化学
缓蚀剂
极化(电化学)
化学
电极
化学工程
冶金
有机化学
复合材料
物理化学
工程类
复合数
作者
Yuwei Ye,Dongping Yang,Hao Chen,Shengda Guo,Qiumin Yang,Liyong Chen,Haichao Zhao,Liping Wang
标识
DOI:10.1016/j.jhazmat.2019.121019
摘要
Novel N-doped carbon dots (CDs) were obtained through pyrolysis of ammonium citrate at 180 °C for 1, 2 and 3 h, and their corrosion inhibition effect on Q235 steel in 1 M HCl solution were evaluated through electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (Tafel), scanning vibrating electrode technique (SVET) analysis. The changes of corrosion current density and impedance modulus of Q235 steel in inhibitor solutions showed that the as-prepared carbon dots presented a valid protective effect on steel in 1 M HCl solution. Meanwhile, the inhibition efficiency of three carbon dots exceeded 90% at 200 mg/L and the highest inhibitive efficiency was found for the carbon dots prepared at the reaction time of 2 h. The adsorption mechanism of all as-prepared carbon dots complied with the Langmuir adsorption model, containing chemical and physical adsorptions, which was also confirmed by X-ray photoelectronic spectroscopy (XPS) analysis.
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