钙钛矿(结构)
氧化物
电极
化学
过渡金属
化学稳定性
电化学
金属
固溶体
化学工程
无机化学
催化作用
物理化学
结晶学
生物化学
工程类
有机化学
作者
S.Ya. Istomin,Н. В. Лысков,Г. Н. Мазо,Evgeny V. Antipov
出处
期刊:Russian Chemical Reviews
[Turpion]
日期:2020-10-02
卷期号:90 (6): 644-676
被引量:50
摘要
The review addresses and highlights the main results of research on the physicohemical properties of single-phase and composite materials based on transition metal oxides in relation to their practical application as electrode materials for symmetrical solid oxide fuel cells. The electronic structures and thermodynamic stability of transition metal oxides with the perovskite structure are discussed. A detailed consideration is given to the thermal behaviour, chemical stability, electrical conductivity and electrochemical properties of a broad range of electrode materials based on iron-, chromium- and manganese-containing perovskite-like oxides and oxides that crystallize in other structure types. The analysis revealed the most promising compositions of electrode materials for symmetrical solid oxide fuel cells and effective approaches to the improvement of their functional characteristics. The bibliography includes 202 references.
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