材料科学
电介质
涂层
复合材料
纳米复合材料
聚合物
聚合物纳米复合材料
介电强度
电容器
纳米颗粒
填料(材料)
纳米技术
电压
电气工程
光电子学
工程类
摘要
Abstract This report traces the leading scientific endeavors to enhance the dielectric strength of polymer dielectrics for energy storage and electrical insulation applications. Remarkable progress has occurred over the past 15 years through nanodielectric engineering involving inorganic nanofillers, coatings, and polymer matrices. This article highlights the challenges of dielectric polymers primarily toward capacitors and cable/wire insulation. It also summarizes several major technical approaches to enhance the dielectric strength of polymers and nanocomposites, including nanoparticle incorporation in polymers, filler‐polymer interface engineering, and film surface coating. More attention is directed to interface contributions, including rational design of core‐shell structures, use of low‐dimensional fillers and thermally conducting fillers, and inorganic surface coating of polymer films. These efforts demonstrated the enhancement in dielectric strength by 40–160% when controlling the fillers below 5 wt% in polyvinylidenedifluoride (PVDF) composites. This article also discussed the possible dielectric mechanisms and the positive role of interfaces against charge transport traps for attaining higher breakdown strength. The investigation of low‐dimensional filler/coating materials of high thermal conductivity can be key scientific subjects for future research.
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