环氧树脂
材料科学
热固性聚合物
固化(化学)
腰果酚
双酚A
涂层
傅里叶变换红外光谱
溶剂
合成树脂
复合材料
化学工程
有机化学
化学
工程类
作者
Lucas Renan Rocha da Silva,Francisco Avelino,Otilio Braulio Freire Diógenes,Vinicius de Oliveira Fidelis Sales,Kássia Teixeira da Silva,Walney Silva Araújo,Selma Elaine Mazzetto,Diego Lomonaco
标识
DOI:10.1016/j.porgcoat.2019.105449
摘要
Epoxy resins are a versatile class of thermosetting precursors. The most commonly used compound in the production of these resins has been bisphenol A (BPA). However, due to its proven toxicity, one of the biggest challenges has been replacing BPA with renewable and non-toxic phenols. In this sense, novel epoxy coatings were prepared from the direct valorization of the cashew nutshell liquid (CNSL) as alternatives anticorrosive coatings for steel. The epoxy resin was obtained by epoxidation of double bonds in the aliphatic chain of cardanol and cardol using in situ performic acid generated by a solvent-free methodology. The chemical structure of the resin was evaluated by spectroscopic techniques such as FTIR and 1H and 13C NMR. For the coatings preparation, epoxidized-CNSL (e-CNSL) resin was cured with different curing agents (DETA, IPDA and PFDA) and the resultant thermosettings were analyzed regarding their chemical, thermal, mechanical and anticorrosive properties using the DGEBA/IPDA coating as reference. The anticorrosive properties of the coatings were evaluated by electrochemical impedance spectroscopy. The results showed that e-CNSL-based coatings have great potential as bio-based coatings for corrosion protection, being an interesting alternative to replace the current BPA-based materials.
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