电磁干扰
材料科学
复合材料
电磁干扰
电磁屏蔽
石墨烯
聚氨酯
氧化物
复合数
自愈
纳米技术
冶金
计算机科学
医学
电信
替代医学
病理
作者
Haiyang Li,Xuanhe Ru,Ying Song,Huanping Wang,Chenhui Yang,Lei Gong,Zhen‐Guo Liu,Qiuyu Zhang,Yanhui Chen
标识
DOI:10.1016/j.compscitech.2022.109602
摘要
As the application environment of electromagnetic interference (EMI) shielding composites becomes increasingly complex and changeful, the polymer materials with excellent mechanical properties and EMI shielding effectiveness (EMI SE) are highly desired, in order to maintain the long-term operation of equipment. Herein, we report a series of flexible and self-healing EMI shielding composites, which are developed by first constructing a highly electrically conductive 3D porous Ti3C2Tx MXene/reduced graphene oxide (rGO) hybrid aerogel (MRG) by the freeze-drying and chemical reduction methods, and subsequently introducing dynamic crosslinked polyurethane containing Diels–Alder bonds (PUDA) into MRG by the vacuum assisted impregnation method. The 3D MXene/rGO/PUDA (MRGP) composites show a high EMI SE of 39.1 dB at an ultra-low 0.46 vol% of MXene and 0.65 vol% of rGO loading in the range of X-band (8.2–12.4 GHz), and the EMI SE can recover to 34.1 dB after three times of severing/healing cycles, retaining 91.4% of the EMI SE of the initial sample. In addition, the EMI SE of thrice healed MRGP composite hardly changes after 5000 bending cycles. The flexible and self-healing EMI shielding PUDA composites in our work show great potential application for long-term protection of portable communication electronic equipment.
科研通智能强力驱动
Strongly Powered by AbleSci AI