氢解
5-羟甲基糠醛
产量(工程)
化学
可重用性
羟甲基糠醛
金属有机骨架
多相催化
催化作用
有机化学
材料科学
吸附
糠醛
软件
计算机科学
冶金
程序设计语言
作者
Kaili Zhang,Qinglei Meng,Haihong Wu,Mingyuan He,Buxing Han
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2022-07-25
卷期号:10 (31): 10286-10293
被引量:19
标识
DOI:10.1021/acssuschemeng.2c02393
摘要
2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels, which can be produced from biomass-derived 5-hydroxymethylfurfural (5-HMF). Efficient catalysts for selective hydrogenolysis of HMF to DMF under mild conditions without any additives are highly desired. Herein, we designed and prepared a Zr-based metal–organic framework (MOF-808) supported Pd catalyst (Pd/MOF-808), which can efficiently catalyze the hydrogenolysis of HMF to DMF with a yield of 99% under 100 °C without any additives. In addition, the Pd/MOF-808 catalyst also showed good reusability, with the capability of being used five times without loss of activity.
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