Metal–Organic Framework-Derived BiIn Bimetallic Oxide Nanoparticles Embedded in Carbon Networks for Efficient Electrochemical Reduction of CO2 to Formate

Bismuth-based catalysts exhibit excellent activity and selectivity for the electroreduction of carbon dioxide (CO2). However, single-component bismuth-based catalysts are not satisfactory for the electrochemical reduction of CO2 to formic acid, mainly due to their high hydrogen production, low electrical conductivity, and small catalytic current density. Herein, we used a coordination strategy to recombine Bi and In at the molecular level to form Bi/In bimetallic metal-organic frameworks (MOFs), which were then calcined to obtain MOF-derived Bi/In bimetallic oxide nanoparticles embedded in carbon networks. Thanks to the synergistic effect of bimetallic components, high specific surface area, suitable pore size distribution, and high electrical conductivity of the carbon network, the material exhibits excellent activity and selectivity for electroreduction of CO2 to formate. In H-type electrolyzers, the formate Faradaic efficiency reaches 91% at -0.9 V (vs RHE) and does not decrease significantly within 48 h. In situ Fourier transform infrared spectroscopy confirms the reaction intermediates and reveals that CO2 electroreduction is dominant by the *OCHO pathway.