亚甲蓝
吸附
阳离子聚合
废水
化学
体积流量
刚果红
选择性
海绵
甲基蓝
弗伦德利希方程
朗缪尔吸附模型
核化学
化学工程
色谱法
朗缪尔
有机化学
废物管理
催化作用
工程类
物理
生物
光催化
量子力学
植物
作者
Mohd Arish Usman,Anees Y. Khan
标识
DOI:10.1016/j.jhazmat.2022.128238
摘要
Dyes are well known for their hazardous impacts on public health and the environment. Dye removal using monolithic adsorbents is an attractive approach for industrial applications and process design owing to their utilization in both static and dynamic adsorption experiments. In the present work, polyethyleneimine (PEI) based macroporous monolithic sponge (S100) was engineered by ice-templating method and used as an adsorbent. Both batch and continuous operations for dye removal were studied. The effect of various parameters such as pH, adsorbent amount, flow rate, influent dye concentration, and adsorbent bed height on adsorption performance of S100 was studied and modelled using Langmuir/Freundlich isotherms for static operations and Adam-Bohart/Thomas model in packed-bed column experiments. Under optimum conditions, the adsorbent showed a remarkably higher adsorption capacity towards CR (1666.67 mg/g), which is considerably higher than most PEI-based adsorbents. Amine groups in S100 offered exceptional selectivity for anionic Congo red (CR) against cationic Methylene blue (MB) dye (separation factor of 208 and 87 in absence and presence of sodium chloride, respectively). It can be easily regenerated in alkaline medium without a significant loss in percent adsorption capacity and shows good thermal and mechanical stability. Notably, in column studies, a relatively smaller percentage of unused bed height (32.3%) was observed with higher dye uptake for 16 mg S100 at flow rate 10 mL/h and inlet concentration 300 mg/L. Thus, the adsorbent displays an outstanding physiochemical characteristic, excellent selectivity for anionic dye, ease of regeneration and high adsorption performance in both batch and continuous studies.
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