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Machine learning‐based analysis and prediction of the interfacial corrosion processes of copper cathode plates during the electrolytic production of copper powders

腐蚀 电解质 阴极 材料科学 电解 电解法 冶金 电极 化学 工程类 电气工程 物理化学
作者
Youzhi Zhou,Pengcheng Lin,Xin Ke,Qiang Hu,Qi Shi,Jingguo Zhang,Zhong Wang,Limin Wang
出处
期刊:Materials and Corrosion-werkstoffe Und Korrosion [Wiley]
卷期号:73 (5): 811-825
标识
DOI:10.1002/maco.202112977
摘要

Abstract Present efforts to support the essential industrial‐scale electrolytic production of copper‐based metal powders urgently require approaches to the real‐time predicting of corrosion of copper cathodes employed in electrolytic production processes. However, current approaches are extremely limited owing to the difficulty of accurately modeling the complex cathode corrosion process. In this study, the corrosion process under different parameters was analyzed by a self‐designed continuous electrolytic corrosion experimental device, clarify the influence mechanism of current density on the corrosion of the solid–liquid–gas interface area, and addresses this issue by applying a random forest machine learning approach based on three process parameters, including the electrolyte temperature, liquid‐level fluctuation cycle period, and current density. The dataset employed in the model is obtained using a novel experimental corrosion test method based on electrode arrays. The experimental results include the corrosion rates of copper cathode plates at different positions relative to the liquid electrolyte level during the electrolysis process. The resulting stochastic model is demonstrated to obtain a high prediction accuracy of 97% for the various regions of copper cathode plates defined according to liquid electrolyte level.

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