介孔材料
杂原子
碳纤维
电化学
催化作用
甲醇
材料科学
兴奋剂
电子转移
化学工程
多孔性
介孔二氧化硅
模板方法模式
金属
纳米技术
化学
无机化学
电极
物理化学
有机化学
复合材料
冶金
工程类
复合数
光电子学
戒指(化学)
作者
Zaoxue Yan,Lina Gao,Chengjing Dai,Mingmei Zhang,Xiaomeng Lv,Pei Kang Shen
标识
DOI:10.1016/j.ijhydene.2018.01.013
摘要
Carbon materials with more exposed N or S atoms result in higher activity for oxygen reduction reaction. In this paper, mesoporous carbon based materials with 5.3 at% of N and 7.1 at% of S are synthesized (defined as porous-S-N-C). The solid core mesoporous shell silica as template results in mesoporous structure of the porous-S-N-C which favors mass transfer and higher doping (both increase by ∼20%) and exposing of active N and S atoms. The electrochemical characterization results show that the mesoporous structure and the S modification favor much to the N-C based catalysts in catalyzing ORR. Typically, the porous-S-N-C has a 3.99 electron transfer number at 0.4 V, and higher ORR efficiency, much better CO tolerance, much better methanol tolerance and much higher electrochemical stability than commercial Pt/C. This novel method of improving the contents of doped and exposed N and S atoms is imagined to be applied to preparation of other high-content-heteroatom doped materials.
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