Multifunctional Superwettable Material with Smart pH Responsiveness for Efficient and Controllable Oil/Water Separation and Emulsified Wastewater Purification

Developing multifunctional superwettable materials is highly demanded in the oil/water separation field but remains challenging due to the critical limitations of complex fabrication strategy and high cost. Herein, based on the cost-effective kaolin nanoparticles, we present a convenient and mild strategy for fabricating a smart superwettable material with multiple excellent performances, such as pH-responsive water wettability, self-cleaning property, favorable buoyancy, and air purification performance. By virtue of the dual rough surface structure and special chemical composition, the resultant material surface exhibits a superior pH-dependent wettability, which can be reversibly switched between superamphiphobicity and superhydrophilicity–superoleophobicity for many times in accordance with the pH value of the corresponding aqueous solution. As a result, the obtained superwettable material with reversible and controllable water wettability can be applied in efficient and continuous separation of multiple types of oil/water mixtures, especially the highly emulsified oil/water emulsions, via in situ or ex situ wettability change. To our knowledge, the smart material with the wetting property of superamphiphobicity that can be used for continuous emulsified wastewater purification has been rarely discussed in the emerging research works. In addition, the as-prepared material presents universal applicability to diversiform substrates and exhibits robust durability and stability against high-concentration salt solutions and rigorous mechanical abrasion. All of these above-mentioned advantages indicate that the as-prepared superwettable material will hold great potential in various practical applications, including oily wastewater remediation, smart aquatic device fabrication, liquid droplet manipulation, guiding liquid movement, and optimizing multiple operations in industrial fields.