氧化剂
化学
试剂
充氧
组合化学
金属
有机化学
药物化学
生态学
生物
作者
Fan Xu,Xiang‐Yang Qian,Yanjie Li,Hai‐Chao Xu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2017-11-20
卷期号:19 (23): 6332-6335
被引量:61
标识
DOI:10.1021/acs.orglett.7b03152
摘要
An unprecedented electrochemical aromatic C–H oxygenation reaction for the synthesis of 4H-1,3-benzoxazines from easily available N-benzylamides is reported. These oxidative cyclization reactions proceed in a transition metal- and oxidizing reagent-free fashion and produce H2 as only theoretical byproduct. Adapting the C–H oxygenation reaction in an electrochemical microreactor has been demonstrated.
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