对称化
化学
对映选择合成
芳基
催化作用
二胺
配体(生物化学)
组合化学
有机化学
手性配体
药物化学
立体化学
生物化学
受体
烷基
作者
Yong Zhang,Qiuyan Wang,Ting Wang,Huan He,Wenqiang Yang,Xinhao Zhang,Qian Cai
标识
DOI:10.1021/acs.joc.6b02646
摘要
An enantioselective desymmetric aryl C–O coupling reaction was demonstrated under the catalysis of CuI and a chiral cyclic diamine ligand. A series of chiral oxygen-containing heterocyclic units such as 2,3-dihydrobenzofurans, chromans, and 1,4-benzodioxanes with tertiary or quaternary stereocarbon centers were synthesized with this method. DFT calculations were also carried out for a better understanding of the model for enantiocontrol.
科研通智能强力驱动
Strongly Powered by AbleSci AI