乙炔
催化作用
选择性
乙烯
材料科学
纳米颗粒
催化加氢
纳米技术
化学
有机化学
作者
Shihong Zhou,Chenyang Lu,Wenyu Zhou,Yi Bi,Cailong Zhou,Aonan Zeng,Anjie Wang,Luxi Tan,Lichun Dong
摘要
The development of non-noble metal catalysts for selective hydrogenation still remains a challenge. Herein, NiCu@carbon core-shell nanoparticles supported on Al2O3 (NiCu@C/Al2O3) were prepared, which showed enhanced catalytic performance of acetylene-selective hydrogenation in comparison with NiCu/Al2O3 without carbon encapsulation. In detail, NiCu@C/Al2O3 displayed high ethylene selectivity (>86%) even at an acetylene conversion of 100% and excellent stability (>90 h). Thus, NiCu@C/Al2O3 exhibited great potential as an alternative to Pd-based catalysts for acetylene-selective hydrogenation.
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