Bionic Construction of Helical Bi2O3 Microfibers for Highly Efficient CO2 Electroreduction

Abstract Helical Bi 2 O 3 microfibers (HBM) were prepared with the assistance of cotton template through a simple heating treatment in air. This twisted structure induced the lattice strains, enriched the oxygen vacancies of Bi 2 O 3 , and promoted the sufficient exposure of active sites simultaneously, thus performing outstanding activity and selectivity as catalyst for CO 2 electroreduction to formate. The faradaic efficiency (FE) of formate reached 100.4±1.9 % at −0.90 V vs. reversible hydrogen electrode (RHE) in an H‐cell, and the partial current density was boosted to 226 mA cm −2 with FE formate of 96 % at −1.08 V vs. RHE in a flow cell. This work may open a new era for construction of metal oxide fibers by bionic strategy as high‐performance electrocatalysts.