化学
吡嗪
金属有机骨架
锂(药物)
氧化还原
阴极
电池(电)
储能
导电体
超级电容器
纳米技术
电极
电化学
化学工程
无机化学
立体化学
有机化学
材料科学
医学
功率(物理)
物理
物理化学
吸附
量子力学
工程类
复合材料
内分泌学
作者
Xiaoxiao Sun,Xiaoli Yan,Keming Song,Qian Zhang,Zongfan Yang,Xi Su,Weihua Chen,Long Chen
标识
DOI:10.1002/cjoc.202200819
摘要
Comprehensive Summary The merits of intrinsic electrical conductivity, high specific surface area, tunable chemical composition and tailor‐made properties enable two‐dimensional conductive metal‐organic frameworks (2D c‐MOFs) as promising next‐generation electrode materials in the field of energy storage and conversion. Herein, we have designed and synthesized a novel pyrazine‐based 2D c‐MOF (TPQG‐Cu‐MOF) bearing extended π‐conjugated structure and abundant redox active sites. Thanks to the excellent redox reversibility of pyrazine units and CuO 2 units, as well as the insolubility of the rigid framework skeleton, TPQG‐Cu‐MOF as the cathode material of lithium‐ion battery exhibits a reversible specific capacity (150.2 mAh·g –1 at 20 mAh·g –1 ), good cycling stability (capacity retention of 82.6% after 500 cycles at 1 A·g –1 ) and excellent rate performance. Comprehensive ex‐situ spectroscopic studies revealed the reversible redox activity of pyrazine units and CuO 2 units of TPQG‐Cu‐MOF during the Li + insertion/extraction process. The deepening fundamental understanding of the structure‐property relationship was proposed, which might pave the way for further development of efficient MOF‐based energy storage devices.
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