钒
插层(化学)
阴极
材料科学
化学工程
氧化钒
水溶液
电化学
氮化物
无机化学
多孔性
电极
化学
纳米技术
有机化学
复合材料
物理化学
工程类
图层(电子)
作者
Ziyan Yuan,Xuhui Yang,Chuyuan Lin,Peixun Xiong,Anmin Su,Yixing Fang,Xiaochuan Chen,Haosen Fan,Fuyu Xiao,Mingdeng Wei,Qingrong Qian,Qinghua Chen,Lingxing Zeng
标识
DOI:10.1016/j.jcis.2023.02.112
摘要
Rechargeable aqueous zinc-ion batteries have great promise for becoming next-generation storage systems, although the irreversible intercalation of Zn2+ and sluggish reaction kinetics impede their wide application. Therefore, it is urgent to develop highly reversible zinc-ion batteries. In this work, we modulate the morphology of vanadium nitride (VN) with different molar amounts of cetyltrimethylammonium bromide (CTAB). The optimal electrode has porous architecture and excellent electrical conductivity, which can alleviate volume expansion/contraction and allow for fast ion transmission during the Zn2+ storage process. Furthermore, the CTAB-modified VN cathode undergoes a phase transition that provides a better framework for vanadium oxide (VOx). With the same mass of VN and VOx, VN provides more active material after phase conversion due to the molar mass of the N atom being less than that of the O atom, thus increasing the capacity. As expected, the cathode displays an excellent electrochemical performance of 272 mAh g-1 at 5 A g-1, high cycling stability up to 7000 cycles, and excellent performance over a wide temperature range. This discovery creates new possibilities for the development of high-performance multivalent ion aqueous cathodes with rapid reaction mechanisms.
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