锌
阳极
柠檬酸
水溶液
无机化学
蚀刻(微加工)
材料科学
化学
剥离(纤维)
化学工程
电极
冶金
纳米技术
复合材料
有机化学
物理化学
工程类
图层(电子)
作者
Bin-bin Sui,Weijia Song,Lin Sha,Pengfei Wang,Zhe Gong,Yuhang Zhang,Yuhan Wu,Lina Zhao,Junjie Tang,Fa‐Nian Shi
标识
DOI:10.1016/j.ssi.2023.116437
摘要
Aqueous zinc-ion batteries (AZIBs) are expected to be the next generation of energy storage devices, but severe dendrite growth hindering the large-scale application of AZIBs. In this paper, a citric acid (CA) etching method is used to optimize zinc anode, which is referred to as CA-Zn. After citric acid etching, the zinc anode surface was exposed to a high proportion of (002) crystal planes, and the stable (002) crystal planes inhibited the formation of zinc surface by-products. Moreover, acid etching etched micro-grooves on the zinc surface, which increased the electrochemically active surface area of the zinc anode. And the plating/stripping kinetics of Zn/Zn2+ was enhanced. Consequently, the CA-Zn symmetric battery has a stable cycle of 550 h at 1 mA cm−2 and 1 mAh cm−2. AZIBs composed of CA-Zn and activated carbon showed a specific capacity of up to 83.5 mAhg−1 and CE close to 100% during cycling 1500 cycles at a current density of 0.5 A g−1. This paper explores a new method to protect zinc metal by citric acid etching, which provides a new idea for future research.
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