化学
铋
无定形固体
锡
氧化锡
尿素
氧化物
联轴节(管道)
化学工程
无机化学
纳米技术
冶金
有机化学
材料科学
工程类
作者
Xiangyu Chen,Shuning Lv,Hongfei Gu,Hanke Cui,Gui Liu,Yifei Liu,Zhaoyu Li,Ziyan Xu,Jianxin Kang,Gilberto Teobaldi,Limin Liu,Lin Guo
摘要
Closing the carbon and nitrogen cycles by electrochemical methods using renewable energy to convert abundant or harmful feedstocks into high-value C- or N-containing chemicals has the potential to transform the global energy landscape. However, efficient conversion avenues have to date been mostly realized for the independent reduction of CO2 or NO3–. The synthesis of more complex C–N compounds still suffers from low conversion efficiency due to the inability to find effective catalysts. To this end, here we present amorphous bismuth–tin oxide nanosheets, which effectively reduce the energy barrier of the catalytic reaction, facilitating efficient and highly selective urea production. With enhanced CO2 adsorption and activation on the catalyst, a C–N coupling pathway based on *CO2 rather than traditional *CO is realized. The optimized orbital symmetry of the C- (*CO2) and N-containing (*NO2) intermediates promotes a significant increase in the Faraday efficiency of urea production to an outstanding value of 78.36% at −0.4 V vs RHE. In parallel, the nitrogen and carbon selectivity for urea formation is also enhanced to 90.41% and 95.39%, respectively. The present results and insights provide a valuable reference for the further development of new catalysts for efficient synthesis of high-value C–N compounds from CO2.
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