On the Similarity and Differences Between Nano-Enhanced Laser-Induced Breakdown Spectroscopy and Nano-Enhanced Laser-Induced Plasma Spectroscopy in Laser-Induced Nanomaterials Plasma

The interaction of pulsed lasers with matter involving nanomaterials as a pure target or thin layer deposited on a target initiates transient plasma, which shows strong enhancement in a spectral line emission. This domain of research has been explored via two well-established techniques dubbed NELIBS and NELIPS. These Nano-Enhanced Laser-Induced Breakdown or Plasma Spectroscopy techniques entail similarities as well as differences. The newly defined concept of Nano-Enhanced Laser-Induced Plasma Spectroscopy NELIPS is introduced. Thereupon, certain confusion has arisen from various aspects of the similarities as well as differences between the two techniques. In this article, we will investigate the application of either technique to retrieve relevant data about the enhanced spectral line plasma emission phenomenon. To discriminate between these two techniques, a survey on the nature of the target, the origin of enhancement and prevalent theoretical approaches is presented. In this context, the potential achievements, challenges and expected prospects are comparatively highlighted. This review emphasizes the unique contributions of NELIPS, particularly the advanced approach in nanoscale thermal modeling and spectroscopic applications.