The rate performance of biomass-based hard carbon has always been one of the obstacles to its large-scale use. There are various challenges in improving the rapid conduction of sodium ions at the interface and realizing the efficient utilization of inactive carbon in large current. In this study, a disorder-in-ordered nanostructure carbon front-face coated with hard carbon which forms a heterogeneous carbon is prepared by coulomb adsorption of methylene blue and alkalized kapok fiber. A study on heterogeneous hard carbon material formation is proposed by incorporating heteroatoms at different carbonization temperatures. When the current density increases to 10 A g