Macrocyclic Supramolecular Glass: New Type of Supramolecular Transparent Materials

Abstract Transparent materials are widely used in industries, everyday life, and scientific activities. The development of new, lightweight, and durable artificial transparent materials is a challenge in synthetic chemistry. In this study, a supramolecular approach is conceived to construct transparent glass. Cyclodextrins are selected as the building blocks for the fabrication of supramolecular glass via noncovalent polymerization. The newly formed glass displays several attractive advantages, including good thermal processability, high mechanical strength and dielectric constant, excellent visible light transparency, and good adhesion performance. Importantly, the structural characteristics of long‐range disorder and short‐range order are observed in cyclodextrin glass. Here a new strategy is presented for the preparation and functionalization of low‐molecular‐weight transparent materials.