非平衡态热力学
统计物理学
稳态(化学)
马尔可夫链
物理
财产(哲学)
马尔可夫过程
理论物理学
数学
量子力学
化学
统计
物理化学
哲学
认识论
作者
Jacob Calvert,Dana Randall
标识
DOI:10.1073/pnas.2411731121
摘要
The global steady state of a system in thermal equilibrium exponentially favors configurations with lesser energy. This principle is a powerful explanation of self-organization because energy is a local property of configurations. For nonequilibrium systems, there is no such property for which an analogous principle holds, hence no common explanation of the diverse forms of self-organization they exhibit. However, a flurry of recent empirical results has shown that a local property of configurations called “rattling” predicts the steady states of some nonequilibrium systems, leading to claims of a far-reaching principle of nonequilibrium self-organization. But for which nonequilibrium systems is rattling accurate, and why? We develop a theory of rattling in terms of Markov processes that gives simple and precise answers to these key questions. Our results show that rattling predicts a broader class of nonequilibrium steady states than has been claimed and for different reasons than have been suggested. Its predictions hold to an extent determined by the relative variance of, and correlation between, the local and global “parts” of a steady state. We show how these quantities characterize the local-global relationships of various random walks on random graphs, spin-glass dynamics, and models of animal collective behavior. Surprisingly, we find that the core idea of rattling is so general as to apply to equilibrium and nonequilibrium systems alike.
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