Dynamics of Polymer Films on Polymer-Grafted Substrates: A Molecular Dynamics Simulation

For substrate-supported polymer films, the tails of adsorbed chains are generally assumed to play important roles in the propagation of the substrate's effect inside polymer films. The effects of the grafting density and the rigidity of substrate-grafted polymers, the simplest model for the adsorbed tails, on the diffusivity of film polymers are investigated by performing molecular dynamics simulations. An optimal grafting density σ