Green and Scalable Synthesis of a Dual-ligand Zn-MOF with Unprecedented Space-time Yield in Aqueous Media and Efficient CH4/N2 Separation

A pioneering green and scalable modulator/base co-regulation strategy was developed, enabling the kg-scale synthesis of a dual-ligand Zn-MOF in water with a superior space–time yield, offering a promising material for industrial CH 4 /N 2 separation.