阳极
材料科学
钾
硫黄
扩散
多孔性
碳纤维
化学工程
氮气
氢氧化钾
兴奋剂
离子
微观结构
吸附
纳米技术
复合材料
化学
电极
复合数
光电子学
有机化学
冶金
热力学
工程类
物理
物理化学
作者
Guilan Li,Anding Xu,Fulan Zhong,Cunke Huang,Hao Sun,Zhiguang Xu,Songping Wu,Yurong Yan
标识
DOI:10.1002/batt.202100379
摘要
Abstract Carbonaceous materials are regarded as prospective anode candidates of potassium‐ion batteries. However, the rate capability and cycling stability of classic carbon materials are still far from satisfactory. Herein, we exploit a facile and low‐cost strategy to enable the precise synthesis of sulfur/nitrogen co‐doped in‐plane porous carbon nanosheets with fishnet‐shaped microstructure (SN‐CNSs). The well‐designed in‐plane porous structure and the interconnected carbon flake network can accelerate the diffusion of potassium ions, alleviate volume expansion, and provide sufficient active sites. As a result, the SN‐CNSs deliver an impressively reversible capacity of 248 mAh g −1 at a current density of 1 A g −1 after 4500 cycles, and an excellent rate capacity of 137.3 mAh g −1 after 4000 cycles under 5 A g −1 . Density functional theory (DFT) calculations further verify the advantage of S/N co‐doping in the adsorption/diffusion of K‐ion in SN‐CNSs materials. Such an excellent performance shows that SN‐CNSs possess a great potential to be a superior anode of potassium‐ion batteries.
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