Fast-Charging Anode Materials and Novel Nanocomposite Design of Rice Husk-Derived SiO<sub>2</sub> and Sn Nanoparticles Self-Assembled on TiO<sub>2</sub>(B) Nanorods for Lithium-Ion Storage Applications

材料科学 阳极 纳米棒 纳米复合材料 微观结构 化学工程 纳米颗粒 锂(药物) 纳米技术 无定形固体 电化学 电极 复合材料 化学 结晶学 医学 物理化学 内分泌学 工程类
作者
Thanapat Autthawong,Chawin Yodbunork,Waewwow Yodying,Ruttapol Boonprachai,Orapim Namsar,Aishui Yu,Yothin Chimupala,Thapanee Sarakonsri
出处
期刊:ACS omega [American Chemical Society]
卷期号:7 (1): 1357-1367 被引量:4
标识
DOI:10.1021/acsomega.1c05982
摘要

A novel microstructure of anode materials for lithium-ion batteries with ternary components, comprising tin (Sn), rice husk-derived silica (SiO2), and bronze-titanium dioxide (TiO2(B)), has been developed. The goal of this research is to utilize the nanocomposite design of rice husk-derived SiO2 and Sn nanoparticles self-assembled on TiO2(B) nanorods, Sn-SiO2@TiO2(B), through simple chemical route methods. Following that, the microstructure and electrochemical performance of as-prepared products were investigated. The major patterns of the X-ray diffraction technique can be precisely indexed as monoclinic TiO2(B). The patterns of SiO2 and Sn were found to be low in intensity since the particles were amorphous and in the nanoscale range, respectively. Small spherical particles, Sn and SiO2, attached to TiO2(B) nanorods were discovered. Therefore, the influence mechanism of Sn-SiO2@TiO2(B) fabrication was proposed. The Sn-SiO2@TiO2(B) anode material performed exceptionally well in terms of electrochemical and battery performance. The as-prepared electrode demonstrated outstanding stability over 500 cycles, with a high discharge capacity of ∼150 mA h g-1 at a fast-charging current of 5000 mA g-1 and a low internal resistance of around 250.0 Ω. The synthesized Sn-SiO2@TiO2(B) nanocomposites have a distinct structure, the potential for fast charging, safety in use, and good stability, indicating their use as promising and effective anode materials in better power batteries for the next-generation applications.
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