单线态氧
碳纳米管
过硫酸盐
化学
电子转移
光化学
水溶液
羟基自由基
催化作用
激进的
氧气
化学工程
纳米技术
材料科学
有机化学
工程类
作者
Xin Cheng,Hongguang Guo,Yongli Zhang,Gregory V. Korshin,Bo Yang
出处
期刊:Water Research
[Elsevier]
日期:2019-06-01
卷期号:157: 406-414
被引量:205
标识
DOI:10.1016/j.watres.2019.03.096
摘要
This study aimed to elucidate the intrinsic mechanisms of PS activation by carbon nanotubes (CNTs). Singlet oxygen generation (1O2) and direct CNTs-mediated electron transfer were hypothesized to be two major pathways of the oxidation of 2,4-dichlorophenol (2,4-DCP) by PS in the presence of both unmodified and modified CNTs. For the first time, roles of CNT active sites responsible for PS activation were determined using CNT derivatization and structural characterization. By selectively deactivating the carbonyl, hydroxyl or carboxylic groups on CNTs surface and linear sweep voltammetry (LSV) analysis, CO groups were determined to be the main active sites contributing to the direct electron transfer oxidation, while singlet oxygen was generated at CNTs defects. Subsequent UV irradiation was shown to cause the recovery of surface defects with ID/IG of CNTs increasing by 21%. This resulted in the regeneration of the performance for the coupled system and allowed for multi-cycle activation of PS by CNTs. These results suggest that CNTs/PS system combined with regeneration based on UV irradiation can be used as an effective alternative process for continuous degradation of recalcitrant aqueous contaminants through the non-radical mechanism.
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