化学
光催化
催化作用
酒精氧化
选择性
吸附
醛
光化学
石墨氮化碳
氮化碳
量子产额
基质(水族馆)
产量(工程)
质子化
无机化学
反应性(心理学)
有机化学
材料科学
医学
物理
海洋学
替代医学
病理
量子力学
冶金
荧光
地质学
离子
作者
Chong Wang,Qiang Wan,Jiajia Cheng,Sen Lin,Aleksandr Savateev,Markus Antonietti,Wei Wang
标识
DOI:10.1016/j.jcat.2020.11.021
摘要
Photocatalytic aerobic oxidation of alcohols for the direct synthesis of esters has received significant attention in recent years, but the relatively low efficiency and selectivity under visible light irradiation is the main challenge for their practical applications. Here, surface acidic sites were imparted onto metal-free heterogeneous photocatalysts by the protonation of carbon nitride (HMCN) to promote the activity for the esterification reaction through further adsorption and activation of the intermediate aldehyde. The activation of the substrate could be remarkably modulated through tuning the acidic sites on the surface of the photocatalyst, leading to a controllable reactivity of the catalytic reaction. The one-pot process for the direct aerobic oxidative esterification of alcohol exhibits high efficiency and selectivity under mild and additive-free conditions and the apparent quantum yield (AQY) of the photocatalytic esterification reaction is 0.41% at 420 nm. Moreover, a scalable photocatalytic process by the merging of a continuous flow system with the heterogeneous HMCN photocatalyst is demonstrated, combining high catalytic efficiency and stability at ambient temperatures and being promising for larger-scale applications.
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