Anionic redox in Na-based layered oxide cathodes: a review with focus on mechanism studies

氧化还原 材料科学 阴极 氧化物 过渡金属 电化学 无机化学 化学 催化作用 物理化学 有机化学 电极 冶金
作者
Chao Li,Fushan Geng,Bingwen Hu,Bingwen Hu
出处
期刊:Materials Today Energy [Elsevier BV]
卷期号:17: 100474-100474 被引量:57
标识
DOI:10.1016/j.mtener.2020.100474
摘要

Among the potential cathode candidates for Na-ion batteries (NIBs), Na-based layered transition-metal oxides hold the greatest promise by virtue of their appropriate energy density, environmental benignity, and affordable synthesis. However, the theoretical energy density of most layered oxide cathodes is limited as their charge compensation process relies solely on the cationic redox of transition-metal (TM) ions. To break this shackle, anionic redox has emerged as a lever to improve the energy density of layered oxides. Herein, a systematic overview of the latest progresses on anionic-redox-active layered oxide cathodes is presented, with focus on the mechanism studies of anionic redox reaction. The practical challenges of anion redox in layered oxides are also summarized, and the possible solutions are suggested. In contrast to the Li-ion system, anion redox activity is uncovered for both Na-rich and Na-deficient layered oxides, and their underlying anionic reaction mechanisms exhibit many discrepancies. Moreover, the promise of utilizing sole anionic redox in NIBs with earth-abundant and low-cost elements is also considerable. This overview could provide robust guidance for further development of high-energy layered oxide cathodes with anionic redox activity.
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