成核
冷凝
喷嘴
化学
光散射
热力学
同种类的
相(物质)
散射
经典成核理论
增长率
材料科学
化学物理
机械
光学
物理
有机化学
几何学
数学
作者
C. A. Moses,Gilbert D. Stein
出处
期刊:Journal of Fluids Engineering-transactions of The Asme
[ASM International]
日期:1978-09-01
卷期号:100 (3): 311-322
被引量:237
摘要
A series of experiments on steam condensation have been made in a Laval nozzle over a variety of starting conditions such that the onset of condensation occurs in the range −40 to 40°C (233–313 K). The homogeneous nucleation and growth of the new phase are documented with both static pressure and laser light scattering. Since even at onset the majority of the condensed phase is due to droplet growth the nucleation and growth are coupled and the availability of two measured quantities is helpful in comparing a particular combination of nucleation rate and growth law. For detailed calculations on one of the experiments there is excellent agreement with both measurements throughout the condensation zone and theoretical calculations using the classical nucleation rate expression due to Volmer and droplet growth laws due to Gyarmathy and Hill in which thermal and mass accommodation coefficients are near unity.
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