曲折
电极
材料科学
多孔性
多孔介质
扩散
粒子(生态学)
锂(药物)
显微镜
扫描电子显微镜
分析化学(期刊)
光学
复合材料
化学
物理
热力学
地质学
色谱法
海洋学
内分泌学
物理化学
医学
作者
Martin Ebner,Vanessa Wood
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2014-12-30
卷期号:162 (2): A3064-A3070
被引量:147
摘要
We present an open source software application "BruggemanEstimator" that allows a user to estimate the tortuosity of a porous electrode. BruggemanEstimator determines the Bruggeman exponent based on the Differential Effective Medium approximation and as input requires only two microscope images: one of the top and one of a cross section through an electrode. These images, which can be easily acquired with a scanning electron or optical microscope, are used to extract a sampling of active particle shapes as well as the orientation of the particles within the electrode. We validate the accuracy of BruggemanEstimator by comparing the estimated Bruggeman exponents to values calculated by performing numerical diffusion simulations on three-dimensional microstructures obtained from tomographic techniques.
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