材料科学
阴极
八面体
离子
阳极
法拉第效率
过渡金属
碱金属
化学工程
无机化学
电极
物理化学
催化作用
化学
工程类
有机化学
生物化学
作者
Indeok Lee,Gwangeon Oh,Seulgi Lee,Tae Yeon Yu,Muhammad Hilmy Alfaruqi,Vinod Mathew,Balaji Sambandam,Yang Kook Sun,Jang Yeon Hwang,Jaekook Kim
标识
DOI:10.1016/j.ensm.2021.05.046
摘要
The development of advanced cathode materials with high operational voltage and high reversible capacity is crucial for facilitating the practical realization of sodium-ion battery (SIB) technology. Herein, O3-type Na0.9Ca0.035Cr0.97Ti0.03O2 is designed by co-substitution of Ca and Ti into O3-type NaCrO2, and proposed as a new cathode material for high-energy and practical SIBs. On the basis of the stoichiometry, alkali earth metal ions successfully incorporate into the NaO6 octahedron of NaCrO2 by substituting a single Ca2+ per two Na+, while Ti4+ ions are substituted with Cr3+ ions into the CrO6 octahedral site, resulting in formation of Na+ vacancies in the Na+ layer for the charge compensation. This co-substitution strategy reinforces the structural stability of the O3-type Na0.9Ca0.035Cr0.97Ti0.03O2 cathode, induced by the stronger Ti–O bond than Cr–O bond and presence of immobile Ca2+ ions between the CrO6 slabs. These structural features suppress the irreversible phase transition and provide excellent Na+ ion-diffusion kinetics in a wide operation voltage window of 1.5–3.8 V, allowing the cathode to deliver the high initial Coulombic efficiency of 95% and retain the 90% of its initial capacity after 1000 cycles at a 10 C rate. Moreover, the cathode guarantees the practical applicability with long-term cycling in a pouch-type full cell using a hard carbon anode, as well as with durability against water.
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