Additive Manufacturing of Ti3C2‐MXene‐Functionalized Conductive Polymer Hydrogels for Electromagnetic‐Interference Shielding

The ongoing miniaturization of devices and development of wireless and implantable technologies demand electromagnetic interference (EMI)-shielding materials with customizability. Additive manufacturing of conductive polymer hydrogels with favorable conductivity and biocompatibility can offer new opportunities for EMI-shielding applications. However, simultaneously achieving high conductivity, design freedom, and shape fidelity in 3D printing of conductive polymer hydrogels is still very challenging. Here, an aqueous Ti3 C2 -MXene-functionalized poly(3,4-ethylenedioxythiophene):polystyrene sulfonate ink is developed for extrusion printing to create 3D objects with arbitrary geometries, and a freeze-thawing protocol is proposed to transform the printed objects directly into highly conductive and robust hydrogels with high shape fidelity on both the macro- and microscale. The as-obtained hydrogel exhibits a high conductivity of 1525.8 S m-1 at water content up to 96.6 wt% and also satisfactory mechanical properties with flexibility, stretchability, and fatigue resistance. Furthermore, the use of the printed hydrogel for customizable EMI-shielding applications is demonstrated. The proposed easy-to-manufacture approach, along with the highlighted superior properties, expands the potential of conductive polymer hydrogels in future customizable applications and represents a real breakthrough from the current state of the art.