Effect of Anodic Behavior on Electrochemical Machining of TB6 Titanium Alloy

材料科学 电化学加工 介电谱 计时安培法 喷嘴 腐蚀 阳极 循环伏安法 机械加工 线性扫描伏安法 冶金 复合材料 电化学 电解质 化学 电极 热力学 物理化学 物理
作者
Weidong Liu,Sansan Ao,Yang Li,Zuming Liu,Hui Zhang,Sunusi Marwana Manladan,Zhen Luo,Zhiping Wang
出处
期刊:Electrochimica Acta [Elsevier BV]
卷期号:233: 190-200 被引量:103
标识
DOI:10.1016/j.electacta.2017.03.025
摘要

Jet electrochemical machining is a promising shaping method that has the potential to replace traditional sinking ECM in the industry owing to its flexibility and stability. However, its machining quality is impaired by the occurrence of a unique phenomenon (i.e., the anode cannot be uniformly dissolved with high nozzle travel rate). This paper aims to analyze this unique phenomenon from the viewpoint of anodic behavior and to select the optimum travel rate parameter window. The anodic behavior of TB6 titanium alloy in sodium chloride solution was investigated by linear sweep voltammetry, cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. A time-dependent mechanism of pitting/large localized corrosion/polishing for the anodic interface structure was developed. The full electricity quantity of the equivalent oxide layer capacitor, Q, was proposed as a criterion for the initiation of uniform dissolution state. Subsequently, a novel model that incorporates the parameter Q was developed to account for the effect of anodic behavior. This model is able to predict the machined profile as well as the localized corrosion range. Finally, the effect of nozzle travel rate on jet ECM performance was investigated, and a nozzle travel rate of 10 to 25 μm s−1 was selected as the optimum parameter window in the present work.
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